135,252 (1980) is for a detergent for use in cleaning bathrooms and is particularly directed to removing from bathroom surfaces organic and inorganic substances, such as calcium soaps, free fatty acids, glycerides and compounds containing nitrogen. Tile cleaning is easily effected without erosion of the grout between the tiles, which is often experienced when other acidic cleaners are utilized. A detergent composition according to claim 4 which is at a pH of about 4.0 and comprises by weight about 4% of partially neutralized glutaric acid, about 2% of partially neutralized phosphoric acid, about 2.5% of the condensation product of a linear secondary monoalkanol of about 11 to 15 carbon atoms with about 20 moles of ethylene oxide, about 4% of the monobutyl ether of diethylene glycol, no more than about 5% of adjuvants, and the balance of water. The result obtained is largely due to the utilization of different types of acids mentioned, one to soften the deposit of water insoluble soap and the other to prevent damage to the grout. However, city waters may also be employed, even those of hardnesses of up to 300 p.p.m., although those of hardnesses below 150 p.p.m. U.S. Pat. ;ASSIGNORS:ASZMAN, HARRY W.;BUCK, CHARLES E.;EVERHART, CHERIE H.;REEL/FRAME:004339/0556, PATENT EXPIRED DUE TO NONPAYMENT OF MAINTENANCE FEES UNDER 37 CFR 1.362, SUR LIQUID DETERGENT COMPOSITION, PREPARED FOR ITS PREPARATION AND ITS APPLICATION FOR CLEANING THE FLOOR PLATE WITHOUT ERODING THE SEWING MATERIAL, Acidic liquid detergent for ceramic tiles, ACID, LIQUID, CLEANING AGENT FOR CERAMIC PLATES, WHICH DOES NOT DETERMINE THE Potting Material, ACID, LIQUID CLEANING AGENT FOR CERAMIC PLATES AND METHOD FOR THE PRODUCTION THEREOF, Acidic liquid detergent composition for removing soap scum. The product described is said to be useful for cleaning hard surfaces, such as bathroom surfaces, for example, toilets. 4,032,466 described a thickened acid cleaner concentrate which comprises an inorganic acid, an organic acid, a nonionic surfactant, an anionic surfactant, a flocculating agent, such as iron or aluminum ion, and water. Normally, the corresponding monoethers of ethylene glycol will not be utilized, often because of problems of toxicities or poor performances, but in some circumstances they may be substitutable for the described monoethers of diethylene glycol, especially for the ethyl and hexyl ethers. 1,897,813; 2,493,327; 2,558,167; 2,585,127; 2,593,259; 2,629,626; 2,687,346; 3,162,547; 3,211,659; 3,507,798; 3,650,965; 3,909,437; 3,915,633; 3,953,352; 4,032,466; 4,181,622; 4,235,734; and 4,247,408. COLGATE-PALMOLIVE COMPANY, 300 PARK AVE., NEW YORK, ASSIGNMENT OF ASSIGNORS INTEREST. Among the U.S. patents found are U.S. Pat. The invention has been described with respect to illustrations and working examples thereof but is not to be limited to these because it is evident that one of skill in the art to which this invention pertains, with the present application before him, will be able to utilize substitutes and equivalents without departing from the invention. IMPROVEMENTS TO ACID LIQUID DETERGENT COMPOSITION TO CLEAN CERAMIC TILES WITHOUT EROSIONING THE GROUT AND PROCEDURE FOR ITS OBTAINING, ACID LIQUID DETERGENT COMPOSITION FOR CLEANING CERAMIC TILES WITHOUT EROSION OF JOINTS AND METHODS OF MANUFACTURE AND USE THEREOF. In those cases when the surface being cleaned is slippery after completion of one such cleaning operation (indicating that not all the soap scum has been removed), the operation is repeated and in such repeated operation, which is the treatment for heavy buildups of soap scum on surfaces to be cleaned, the product will be allowed to stay on the surface to be cleaned for a few minutes, e.g., 3 to 5 minutes, before wiping. ASSIGNMENT OF ASSIGNORS INTEREST. Mixtures of the acids, mixtures of the salts and mixtures of acids and salts may also be employed. Still, before the present invention cleaning compositions were not available which were useful for effectively cleaning ceramic tiles and porcelain ware without damaging the grout between such tiles or adjacent to the porcelain. and all parts are by weight. The cleaning solutions made are neutralized to a pH of 4. U.S. Pat. A search in the classified patent files of the United States Patent and Trademark Office has revealed a number of references of different degrees of relevance to the present invention. None of the mentioned publications, either alone or in combination with any others, describes or suggests the broadest inventive concept of this application and no such publication or combination thereof makes the invention or any aspect of it obvious to one of ordinary skill in the art. Instead of the phenyl ether the benzyl ether may sometimes be desirably substituted, and mixtures of such ethers, including mixtures of the aromatic and aliphatic ethers, may also be employed. In an aspect of the invention of intermediate scope the acidic detergent composition comprises a minor proportion of glutaric acid, as the physiologically and aesthetically acceptable non-sequestering acid, and the acid which forms a water insoluble calcium salt may be selected from the group consisting of phosphoric acid, tartaric acid, sulfuric acid, oxalic acid, tungstic acid, cumene sulfonic acid and higher linear alkyl benzene sulfonic acid wherein the higher alkyl is of 10 to 18, preferably 11 to 15 carbon atoms. The cleaner may be applied in similar fashion to glassware and fiberglass panels, such as those in shower doors or tub enclosures, and onto nickel- or chrome-plated faucets, handles and spouts and onto copper and brass parts, which are also satisfactorily cleaned of soap scum buildups without damage to the materials thereof. ACID LIQUID DETERGENT COMPOSITION FOR CLEANING CERAMIC TILES WITHOUT PROCESSING THE FILLING MATERIAL. While, in accordance with the broader aspects of the present invention, combinations of acids which react with calcium and magnesium soaps and those which form water insoluble (and non-soap) calcium salts may be employed with any suitable detergent solutions, including nonionic and anionic detergents and mixtures thereof, it will be highly preferable for the acidic liquid detergent compositions of this invention to comprise, as a detergent, a condensation product of ethylene oxide and higher linear alcohol of 8 to 20 carbon atoms, in which the content of ethylene oxide is at least 20 ethylene oxide groups per mole of the alcohol. In addition to the mentioned U.S. patents, several Japanese patents of interest have been noted. Of course, those acids which are toxic under the circumstance of use will also preferably be avoided. from the surface to be cleaned. No. No. 4. The experiments of Examples 1 and 2 are repeated, with the nonionic detergent condensation product being replaced with similar condensation products wherein the fatty alcohol is a primary or secondary alcohol or mixture thereof of an average of 12, 14 or 16 carbon atoms, and the number of ethylene oxide groups per mole is 20, 30 or 40, respectively. The acidic detergent composition may then be removed by rinsing with a water spray. It may be (and usually is) subsequently partially neutralized to the desired pH range during manufacture of the invented acidic cleaner but it is also within the invention to employ salts of such acid and to convert them to the desired pH, it being recognized that the products of both such operations are the same. In the compositions of this invention the described type and proportion of each component are considered important to the obtaining of a desired product, which is effective to clean ceramic tiles and other bathroom surfaces without eroding grout that will of necessity also be contacted by the detergent composition. Additionally, it acts as a medium which maintains the acids in effective ionized form and in contact with soap scum to facilitate reactions between the acids and the insoluble fatty acid soaps present. Owner name: No. In such nonionic detergents the higher linear alcohol will average the number of carbon atoms indicated and preferably such average will be from 9 to 18 carbon atoms, more preferably 9 to 15 carbon atoms, and most preferably 11 to 15 carbon atoms, e.g., about 13 carbon atoms per mole of the alkanol. The composition is found to be an excellent bathroom cleaner, being especially useful for cleaning soap scum and other soil from ceramic tile, porcelain ware, such as bathtubs and sinks, and from other hard surfaces. Finally, The Chemical Formulary (Bennett) discloses, at p. 233, a gelled rust removing composition comprising Carbitol, nonylphenol ethoxylate, phosphoric acid, hydroxyacetic acid, methyl cellulose and water. Application onto such surfaces is by spraying, with the spray nozzle being at a distance of about 15 to 20 cm. The described nonionic surface active materials will include an average of at least about 20 ethylene oxide groups per mole of the alcohol, preferably from 20 to 100 moles, more preferably 20 to 60 moles, still more preferably 20 to 30 moles, and most preferably about 20 moles of ethylene oxide, on the average. 11. The invented product is comparatively mild to the hands, is easy to employ and consistently yields excellent results. It is of a viscosity approximately that of water or slightly less, but satisfactorily covers and holds to vertical surfaces without excessive dripping when applied in an economical thin, yet effective, "coating" onto surfaces to the cleaned. Japanese Pat. The problem of adequately and easily removing soap scum from ceramic tiles has been known for a long time and water, detergents, acidifying agents and solvents have been suggested for inclusion in tile cleaning compositions. The material will usually be allowed to remain on the surface to be cleaned for a period from 10 seconds to 5 or 10 minutes, but preferably such contact time will be from about 30 seconds to five minutes or from 1 to 3 minutes. 77,111 (1977) describes a bathroom composition which contains one or more types of organic acids and an alkyl, phenyl or benzyl ether or ethylene glycol, diethylene glycol or triethylene glycol. An acidic liquid detergent composition, suitable for cleaning ceramic tiles without eroding grout between them, which comprises a minor proportion of glutaric acid, a lesser minor proportion of phosphoric acid, both acids being partially neutralized to a pH in the range of 3 to 5 and the detergent composition being at such pH, and the partially neutralized glutaric and phosphoric acids being present in such proportions that the proportion of partially neutralized glutaric acid in the composition is effective to remove soap scum from tiles and the proportion of partially neutralized phosphoric acid is effective to inhibit erosion of grout between the tiles by the partially neutralized glutaric acid, a minor proportion of a condensation product of ethylene oxide and higher linear alcohol of 8 to 20 carbon atoms, with the content of ethylene oxide being at least about 20 ethylene oxide groups per mole of the alcohol, which condensation product is effective in acid medium to lift soap scum off the tiles being cleaned, a minor proportion of a mono-lower alkyl ether or phenyl ether of diethylene glycol, wherein the lower alkyl is of 2 to 6 carbon atoms, with the proportion of such monoether of diethylene glycol being effective to assist in removing loosened soap scum from the tiles by helping to transport it away from the location where it was initially bonded to the tiles, and a major proportion of water, in which the partially neutralized glutaric acid, partially neutralized phosphoric acid, condensation product of ethylene oxide and linear alcohol, and diethylene glycol ether are dissolved. The manufacturing method is extremely simple and orders of addition are not usually significant or critical (except that the neutralizing agent will often best be added last to allow for best pH control and to promote rapid attainment of equilibrium). In repeated applications after light soilings with soap scum the wiping step may sometimes be omitted (and is omitted) and the surface being cleaned, whether porcelain or porcelain enamelware, as in a sink or tub, or ceramic tile, such as on bathroom walls or floors, or of shower stalls, tub enclosures or other such hard bathroom surfaces, will be cleaned of the hard to remove soap scum and will be attractively lustrous, without the need for wiping prior to rinsing off of the acidic cleaner. Also, when acetic acid, succinic acid and propionic acid or mixtures thereof are employed in place of the glutaric acid the products made are objectionable because they have unacceptable odors and cause nasal and respiratory irritations due to the presence(s) of such acid(s). 1. While the acidic liquid detergent composition which includes both partially neutralized glutaric and phosphoric acids represents a much preferred aspect of the present invention, more broadly the invention may relate to such a detergent composition which comprises a minor proportion of a non-toxic and physiologically and aesthetically acceptable non-sequestering acid which reacts with calcium and magnesium soaps of higher fatty acids in the soap scum which is adherent to ceramic tiles and grout to be cleaned, so as to loosen the bond of such scum to such tiles, a lesser minor proportion of an acid which forms a water insoluble calcium salt, both acids being partially neutralized to a pH in the range of 3 to 5, a minor proportion of a detersive material, and a major proportion of water, and preferably also contains a minor proportion of a suitable water soluble organic solvent. The compositions of the present invention clean the tile without harming the grout and thus they avoid this serious problem that is associated with other acidic cleaners. However, it is preferred that the acidic components, e.g., glutaric and phosphoric acids, be mixed together with the nonionic detergent condensation product, the monoether of diethylene glycol and the water, and then be partially neutralized to the desired pH range by means of a suitable alkaline neutralizing agent. For best results the composition also includes a solvent which is a mono-lower alkyl ether or phenyl ether of diethylene glycol wherein the lower alkyl is of 2 to 6 carbon atoms. A method according to claim 9 wherein said glutaric acid and phosphoric acid are mixed in the presence of at least some of the water, said aqueous solution of neutralizing agent is added thereto with agitation and said condensation product and said diethylene glycol ether are added thereafter with agitation. The above acidic liquid detergent composition is made by mixing together the various components to produce a solution which has a buffered pH of 4.0. In none of the mentioned publications is a combination of glutaric acid and phosphoric acid mentioned in a liquid cleaner based on nonionic detergent and solvent of the types employed in the compositions of the present application. 3. No. 13. Preferably, before such rinsing, it will be wiped off, as with a cloth or sponge, and sometimes the surface to be cleaned may have the cleaner brushed into vigorous contact with it. Thus, it has been mentioned that salts of the described acids may be partially acidified to the desired pH, and this can be done in the presence or absence of other components of these compositions. Alternatively, the corresponding salts may be employed, as may be mixtures of the acids and/or salts. In use, the compositions of this invention are applied to the surfaces to be cleaned (and the compositions are useful for cleaning other soils than soap scum), preferably by spraying onto ceramic or other surfaces which have been soiled by accumulations of insoluble soaps. No's. Solid detergent composition, reusable cleaning pad containing same and method of manufacture, Fabric rinse composition to remove surfactant residues, Floor cleaning compositions and their use, Acidic liquid detergent compositions for bathrooms, Liquid hard surface cleaning composition with grease release agent, Aqueous cleaning composition for hard surfaces, Aqueous acidic hard surface cleaner with abrasive, Liquid cleaning compositions with grease release agent, Cleaning compositions based on N-alkyl pyrrolidones having about 8 to about 12 carbon atoms in the alkyl group and corresponding methods of use, Multisurface cleaning composition and method of use. detergent compsn. It is taught that the compositions of the patent, which may include acidic substances, surfactant, water soluble solvent and water, are useful for removing stains from bathroom surfaces. This product is intended for cleaning vehicles, such as railroad equipment. When a suitable thickener is added to the formulas of this example or to the formulas of Example 1 a product will be made which flows less readily down a vertical wall onto which it has been sprayed. The cleaning of the tiles by the present compositions is easily effected and in most cases the cleaned tile sparkles and soon recovers its original attractive luster. Such soap scum is usually strongly adherent to the substrate and is difficult to remove with the aid of conventional cleaning materials. Cleanings of the tiles are effected easily and the invented compositions are safter to use, compared with other acidic liquid detergent compositions for this purpose (which are harmful to the grout). In such compositions a minor proportion will be a detergent and a major proportion will be water, such proportions respectively being preferably 1 to 4% and 75 to 90%, more preferably 2 to 3% and 80 to 90%, and most preferably about 2.5% and about 85 to 88%. The detergent is preferably a nonionic detergent, and of such detergents the condensation products of ethylene oxide and higher secondary linear monoalkanol, previously described, are preferred. The adjuvant content of the composition will normally be limited to no more than about 5%, preferably to no more than 3% and most preferably to no more than about 1 or 2%, with the balance of the product normally being water, except for neutralizing agent. Of these a few of the more relevant disclosures will be discussed specifically below. Some such acids may not be sufficiently non-toxic to be employed in retail products for general use and others may be uneconomic, due to high manufacturing costs. Such results are visually apparent after multiple treatments and are verifiable when the grout surfaces are viewed under magnification. Synthetic detergents have been used in tile cleaners and solvents have also been employed in them. The nonionic surface active agent, at the pH described, has an improved detersive action and acts to promote lifting or release of the soap scum from the substrate to which it was previously strongly held. The proportions of the various components of the invented compositions can determine the extent of effectiveness thereof and therefore such should be controlled for best performance of the product. However, citric acid is a sequestering acid and tends to remove calcium from calcium carbonate in the grout employed between adjacent ceramic tiles, which is detrimental to its use, and the other mentioned acids are often unsatisfactory because of unacceptable odors and/or because they result in human nasal and/or respiratory irritation. A method according to claim 11 wherein the acidic detergent composition employed is at a pH in the range of 3.5 to 4.5 and comprises a minor proportion of glutaric acid, a lesser minor proportion of said other acid, which forms a water insoluble calcium salt, both acids being partially neutralized to a pH in the range of 3.5 to 4.5, and the partially neutralized glutaric and said other acid being present in such proportions that the partially neutralized glutaric acid in the composition is effective to remove soap scum from tiles and the partially neutralized said other acid is effective to inhibit erosion of grout between the tiles by the partially neutralized glutaric acid, a minor proportion of a condensation product of ethylene oxide and higher linear alcohol of 8 to 20 carbon atoms, with the content of ethylene oxide being at least about 20 ethylene oxide groups per mole of the alcohol, which condensation product is effective in an acid medium to lift soap scum off the tiles being cleaned, a minor proportion of mono-lower alkyl ether or phenyl ether of diethylene glycol, wherein the lower alkyl is of 2 to 6 carbon atoms, with the proportion of such monoether of diethylene glycol being effective to assist in removing loosened soap scum from the tiles by helping to transport it away from the location where it was initially bonded to the tiles, and a major proportion of water, in which the partially neutralized glutaric acid, partially neutralized said other acid, condensation product of linear alcohol, and diethylene glycol ether are dissolved, the tiles and grout are wiped to remove the acidic liquid detergent composition from them and the tiles and grout are rinsed with water after such wiping. Such grout, which may be of the latex or Portland cement type, normally includes a major proportion of calcium carbonate. It has been found that the desired cleaning effects are obtained without erosion of grout when the proportions of partially neutralized glutaric acid (calculated on the basis of the corresponding unnuetralized glutaric acid) and partially neutralized phosphoric acid (calculated on the basis of the corresponding unneutralized phosphoric acid), or other suitable acids, are in the ranges of 3 to 5% and 0.1 to 3%, respectively, preferably 3.5 to 4.5% and 0.5 to 2.5%, respectively, even more preferably 3.7 to 4.3% and 1.8 to 2.2%, respectively, and most preferably about 4 and 2%, respectively. This application relates to detergent compositions. Liquid detergent composition for hard surfaces, Acidie microemulsion agent for cleaning hard surfaces, Scrub free formulation for cleaning surfaces, Lime soap dispersing agent, detergent composition and cleaning agent composition each containing it, Lapse for failure to pay maintenance fees, Lapsed due to failure to pay maintenance fee, Information on status: patent discontinuation. From the above examples and the preceding specification it is evident that the present invention provides attractive, convenient, economical, effective and efficient means for removing soap scum from bathroom surfaces. Calcium carbonate reacts with acid and therefore the use of acidic cleaners has in the past caused erosion of the grout so that after repeated uses it would become non-adherent and would crack and disintegrate, causing leakage, and eventually requiring replacement. Unless otherwise indicated all temperatures are in C. For example, acetic acid, succinic acid, propionic acid and citric acid may be utilized in some circumstances. The problem of cleaning soap scum from bathroom surfaces, such as sinks, tubs, shower walls and floors, and ceramic tile walls and floors, is one that is well known to every householder. The acid which forms the insoluble calcium salt assists in maintaining the desired pH, helping to attack the soap scum, and at the same time it protects the grout, apparently by protecting the calcium carbonate, which is a major constituent of grouts, against attack by the other acidic component (partially neutralized acids are intended to be covered by this terminology). Liquid acidic hard surface cleaning composition. Nevertheless, in those circumstances when phosphorus-containing materials are to be avoided in detergent products, it may be desirable to substitute another of such acids (or others of equivalent performance) for the phosphoric acid. When the desired proportion of neutralizing agent to produce such pH or other desired pH within the range of 3 to 5 is not known on the basis of previous experiments, the glutaric acid, phosphoric acid, nonionic detergent, monoether of diethylene glycol and water are mixed together, after which sodium hydroxide solution (or other suitable neutralizing agent, such as aqueous KOH or triethanolamine) is admixed, with pH monitoring, until the desired pH is reached. A composition according to claim 6 which is at a pH in the range of 3.5 to 4.5 and comprises a minor proportion of glutaric acid, a lesser minor proportion of said other acid, which forms a water insoluble calcium salt, both acids being partially neutralized to a pH in the range of 3.5 to 4.5, and in which the partially neutralized glutaric and said other acid are present in such proportions that the partially neutralized glutaric acid in the composition is effective to remove soap scum from the tiles and the partially neutralized said other acid is effective to inhibit erosion of grout between the tiles by the partially neutralized glutaric acid, a minor proportion of a condensation product of ethylene oxide and higher linear alchol of 8 to 20 carbon atoms, with the content of ethylene oxide averaging at least about 20 ethylene oxide groups per mole of the alcohol, which condensation product is effective in an acid medium to lift soap scum off the tiles being cleaned, a minor proportion of mono-lower alkyl ether or phenyl ether of diethylene glycol, wherein the lower alkyl is of 2 to 6 carbon atoms, with the proportion of such monoether of diethylene glycol being effective to assist in removing loosened soap scum from the tiles by helping to transport it away from a location where it was initially bonded to the tiles, and a major proportion of water, in which the partially neutralized glutaric acid, partially neutralized said other acid, condensation product of linear alcohol, and diethylene glycol ether are dissolved. A method according to claim 11 wherein said acidic liquid detergent composition contains, in addition, a minor proportion of a detergent selected from the group consisting of anionic detergents, nonionic detergents and mixtures thereof. In other words, the monoether acts to float away the loosened or released and modified soap scum, allowing better access to the remaining held soap scum by the composition, thereby speeding the removal of the soap scum, for which it may also act as a solvent to an extent, The water, in the percentage present, acts as a mutual solvent for the other components, to produce the desired sprayable cleaning solution.